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Detached paint film due to the
action of saline deposits |
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Formation of
saline deposits
This occurs as aggregations of pointed crystals at various
stages of development. The survey data was differentiated
according to whether the saline deposit was at an early stage,
with slight and barely visible blistering of the plaster,
or at an advanced stage where the growth of the crystals causes
the plaster to swell and break up, leading to detachment and
crumbling of the paint film.
From the early 1960s, it became clear that the presence of
saline deposits - one of the main causes of deterioration
in the Chapel's frescoes - was associated with a process of
sulphation in the plaster due to atmospheric pollution. Sulphation
generally takes place in the topmost surface layer of the
plaster (max. depth of 130 microns), but it often reaches
greater depths in areas affected by abrasions and fractures.
The negative action of sulphates is accompanied by that of
nitrates, detected only recently and in considerable quantities.
The presence of chlorides seems to be practically irrelevant.
The formation of saline deposits, at various stages of growth,
occurs in circumscribed areas over the whole surface of the
Chapel frescoes.
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Thin section showing the thrust
of the sulphates on the paint film |
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